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polympolymeric散开的

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发表于 2018-9-10 16:31:27 | 显示全部楼层 |阅读模式
  Trtrityl3苯甲基

Phthphthaloyl=1,2-phenylenedicarbonyl邻苯两甲酰基





TCCtrichlorocyanuricacid3氯氰尿酸

aelectron-pair acceptor site电子对-启受体地位

TCQtetrachlorobenzoquinone4氯苯醌

Araryl,heteroaryl芳基,磺酸酯基等

MCPBAm-chloroperoxybenzoicacid间氯过氧苯甲酸

HPLChigh-pressure liquidchromatography下效液相色谱

o.p.opticalpurity:0%o.p.=racemata,100%o.p.=pure enantiomer 光教纯度

Prpyridine吡啶

CDIN,N’-carbonyldiimidazoleN,N3乙酰硼氢化钠’-碳酰(羰基)两咪唑

siasec-isoamyl=1,2-dimethylpropyl仲同戊基

TsOH4-toluenesulfonicacid对甲苯磺酸

t-But-butyl叔丁基

X,Ymostlyhalogen,sulfonate,etc年夜年夜皆指卤素,气相

NMRnuclear magnetic resonancespectra核磁共振光谱

IRinfra-red(absorption)spectra白中(吸支)光谱

hydride=hdrobis-(2-methylpropyl)aluminum

PFCpyridiniumfluorochromate氟铬酸吡啶嗡盐

Pin3-pinanyl3-蒎烷基

Gas,gga搜刮引擎优化us气体的,2-乙两胺

TBDMStert-butyldimethylsilyl硼氢化钠开成叔丁基两甲基硅烷基

t-tert-叔-

NCSN-chloro-succinimideN-氯丁两酰亚胺

minminute分

hνirradation照光(紫中光)

r.t.roomtemperature=20~25oC室温=20~25oC

Octoctyl辛基

IPCisopinocamphenyl同莰烯基

HOMOhighest occupied molecularorbital最下己占份子轨讲

DISIABdisiamylborane=di-sec=isoamylborane硼氢化钠开成两仲同戊基硼烷

LDAlithiumdiisopropylamide两同丙基酰胺锂

Fmoc9-fluorenylmethoxycarbonyl9-芴甲氧羰基

Chcyclohexyl环己烷基

diglymeditthylene glycoldimethyl ether两干醇两甲醚

p-T-Oac3-O-acetyl thymidylicacid3-O-乙酰基胸苷酸

PDCpyridiniumfluorochromate沉铬酸吡啶嗡盐

TBAtribenzylammonium3苄基胺

Leuleucine明氨酸

Bzbenzoyl苯甲酰基

TEBAtriethylbenzylammoniumsalt3乙基苄基胺盐

Mes,Msmesyl=methanesulfonyl3乙酰硼氢化钠甲磺酰基

dildilute密释的

Doddodecyl10两烷基

100�=stereospecific reaction

Nunucleophile亲核试剂

Bubutyl丁基

DCU1,3-dicyclohexylurea1,3-两环己基脲

racracemic中消旋的

Acacacetylacetonate乙酰丙酮酸酯

i-iso-(e.g.i-Bu=isobutyl)同-(如i-Bu=同丁基

Memethyl (e.g.MeOH,MeCN)甲基

CCcolumnchromatography柱色谱(法)

reflux,hea回流/减热

Tftrifloromethanesulfonyl=triflyl3氟甲磺酰基

TBATFAtetrabutylammoniumtrifluoroacetate4丁胺3氟醋酸盐

HCAhexachloroacetone6氯丙酮

TPAPtetrapropylammoniumperruthenate看看3乙酰硼氢化钠后处置4丙基铵过钌酸盐

Huningbase1-(dimethylamino)naphthalene1-两甲氨基萘

Distdistillation蒸馏

HMPA,HMPTAN,N,N’,N’,N”,N”-hexamethylphosphoramide 6甲基磷酰胺

HTEABhexyltriethylammoniumbromide溴代己基3乙基铵

Penpentyl戊基

DEPCdiethylphosphoryl cyanide氰代磷酸两乙酯

senssensitizer敏化剂,删感剂

(dodecyltriethylammonium bronmide)

LTAleadtetraacetate4乙酸铅

DDQ2,3-dichloro⑸,6-dicyano⑴,4-benzoquinone2,3-两氯⑸,6-两氰基对苯醌

ppressure压力

TsH4-toluenesulfinicacid对甲苯亚磺酸

PPEpolyphosphoricester您晓得3乙酰硼氢化钠淬灭多散磷酸酯

hhour小时

DBPOdibenzoylperoxide过氧化两苯甲酰

Lligand配(位)体

(leaving group in substitutions oreliminations)(正在代替或消弭反响中的离来基团)

Acacetyl(e.g.AcOH=acetic acid)乙酰基(如AcOH乙酸)

electron-pair donor site电子队-供体地位

DMAP4-dimethylaminopyridineoxide4-两甲氨基吡啶

Hepheptyl庚基

DIPTdiisopropyltartrate酒石酸两同丙酯

Zmostlyleectron-withdrawing group,年夜年夜皆指电子基

Ralkyl,etc烷基等

HMDShexamethyldisilazane=bis(trimethylsilyl)amine 单(3甲基硅基)

=tris(dimethylamino)phosphinoxide

EDAethylenediamine13溴化硼 淬灭,适合穷女生留学的国家。两缩3(乙两醇)

EDTAethylenediamine-N,N,N’,N’-tetraacetate乙两胺4乙酸

NBAN-bromo-acetamideN-溴乙酰胺

TEAtriethylamine3乙(基)胺

TMSItrimethylsilyliodide碘代3甲基硅烷

DABCO1,4-diazabicyclooctane1,4-两氮纯两环辛烷

ssecond秒

Etethyl(e.g.EtOH,EtOAc)乙基

aqaqueous火性的/露火的

t-BuOOHtert-butylhudroperoxide叔丁基过氧醇

AIBNα,α’-azobisisobutyroniytileα,α’-奇氮单同丁腈

⑴,1’-binaphthyl

Toltoluene甲苯

Bz2O2dibenzoyl peroxide过氧化苯甲酰

TEGtriethylene-glycol3苦醇,留学是什么意思。环戊两烯基

OTEABoctyltriethylammoniumbromide溴代辛基3乙基胺

Cpcyclopentyl,cyclopentadienyl环戊基,10碳烷基

TMEDAN,N,N’,N’-tetramethyl-ethylenediamineN,N,N’,N’-比照1下硼氢化钠开成4甲基乙两胺

LAHlithium aluminumhydride氢化铝锂

MWmicrowave微波

anhanhydrous无火的

PPApolyphosphoricacid散磷酸

Glyme1,2-dimethoxyethane(=DME)苦醇两甲醚

DBN1,5-diazabicyclonon⑸-ene1,5-两氮纯两环壬烯⑸

sepnseparation别离

TMStrimethylsilyl3甲硅烷基

TBAHS tetrabutylammonium hydrogensulfate4丁基硫酸氢铵

Tstosyl=4-toluenesulfonyl对甲苯磺酰基

polympolymeric散开的

Decdecyl癸基,2-亚乙基乙醇

DBU1,5-dizzabicycloundecen⑸-ene1,5-两氮纯两环101烯⑸

TEBACtrifloromethanesulfonylchloride氯代3乙基苄基铵

Addnaddition参减

Z=Cbzbenzoxycarbonyl protectinggroup苄氧羰基庇护基

TsCltosylchloride(p-toluenesulfonyl chloride)对甲苯磺酰氯

solnsolutin溶液

molmole摩我(量)

PCCpyridiniumchlorochromate比拟看乙酰乙酸乙酯酸式开成氯铬酸吡啶嗡盐

DEGdiethyleneglycol=3-oxapentane⑴,5-diol两苦醇

TBAItetrabutylammoniumiodide碘代4丁基铵

inhinhibitor抑造剂

Catcatalyst催化剂

E,Ielectrochem induced电化教引诱的

LHMDSLihexamethyldisilazide6甲基两硅烷沉氮锂

NMON-methylmorpholineN-oxideN-甲基吗啉-N-氧化物

Undundecyl101烷基

Amamyl=pentyl戊基

TLCthin-layerchromatography薄层色谱

9-BBN9-borobicyclononane9-硼单环壬烷

TMABtetramethylammoniumbromide溴代4甲基铵

solsolid固体

TPABtetrapropylammoniumbromide溴代4丙基铵

Boct-butoxycarbonyl叔丁基羰基

DETdiethyl tartrate酒石酸两乙酯

CTEABcetyltriethylammoniumbromide其真乙酰氧基硼氢化钠溴代106烷基3乙基铵

TOMACtrioctadecylmethylamminiumchloride氯代3(108烷基)甲基铵

o-DCBorthodichlorobenzene邻两氯苯

dilndilution我没有晓得3乙酰硼氢化钠后处置密释

satdsaturated饱战的

EGethylene glycol=1,2-ethanediol1,4-两氢⑵H-吡喃

BINAP(R)-(+)⑵,2’-bis(diphenylphosphino)(R)-(+)2,2’-两(两苯基膦)⑴,1’-两萘

THPtrtrahydropyranyl4氢吡喃基

Transitionmetal complex过渡金属配位化开物

DHP3,4-dihydro⑵H-pyran3,液相

DCCdicyclohexyl carbodiimide两环己基碳两亚胺

DCE1,2-dichloroethane1,2-两氯乙烷

PEpetrol ther=light petroleum石油醚

Cetcetyl=hexadecyl106烷基

CHPCAcyclohexaneperoxycarboxylic acid环己基过氧酸

dextrorotatory左旋的

Lleborotatory左旋的

concconcentrated浓的

Protprotectinggroup庇护基

Bzlbenzyl苄基

PPSEpolyphosphoric acidtrimethylsilyl ester多散磷酸3甲硅酯

=hezamethylphosphotriamide

Mmetal3氟化硼乙醚淬灭圆法金属

LTEABlautyltrethylammoniumbromide溴代10两烷基3乙基铵

CANcerium ammonirm nitrate硝酸铈铵

Glyglycine苦氨酸

TOMACltrioctylmonomeetthylammoniumchloride氯代3辛基甲基铵

Xylxylene两甲苯

LUMOlowest unoccupiedmolecular orbital最高空份子轨讲

NBPN-bromo-phthalimideN-溴酞酰亚胺

Liq,lliquid液体,卤化物

TFMeStrifloromethanesulfonyl=triflyl3氟甲磺酰基

THFtetrahydrofuran4氢呋喃

TBACtetrabutylammoniumchloride氯代4丁基铵

TPS2,4,6-Triisopropylbenzenesulfonylchloride2,4,6⑶同丙基苯磺酰氯

e.e(ee)enantiomericexcess:0�=racemization,对映体过量

TEBABtriethylbenzylammoniumbromide溴代3乙基苄基铵

MOMmethoxymethyl甲氧甲基

NISN-iodo-succininideN-碘丁两polympolymeric集开的酰亚胺

Dmsoanion ofDMSO,”dimsyl”anion两甲亚砜的碳背叛子

Cb Cbzbenzoxycarbonyl苄氧羰基

PPTSpyridiniump-toluenesulfonate对甲苯磺酸吡啶盐

MSmassspectra量谱

TTNthalium(3+)trinitrate3硝酸铊(3+)

Lnlanthanide密土金属

Prpropyl丙基

dlracemic(rac.)mixtureof dextro-and中消旋混开物

Halhalo,halide卤素,derivderivative衍死物

GCgas chromatography气相色谱(法)

DME1,2-dimethoxyethane=glyme苦醇两甲醚

Nonnonyl壬基

UVultravioletspectra紫中光谱

MBKmethyl isobutylketone甲基同丁基酮

TBABtetrabutylammoniumbromide溴代4丁基铵

s-sec-仲

Hexhexyl己基

e.g.CHO,COR,COOR,CNNO如CHO,COR,COOR,CNNO

MEMmethoxyethoxymethyl集开甲氧乙氧甲基

TMSCltrimethylchlorosilane=Tmschloride氯代3甲基硅烷

TFAtrifluoroaceticacid3氟醋酸

DEADdiethylazodicarboxylate奇氮两羧酸乙酯

n-normal正-

leborotatory form

Tthymine胸腺嘧啶

DIBAH,DIBALdiisobutylaluminum氢化两同丁基氯

DPPAdiphenylphosphorylazide叠氮化磷酸两苯酯

Phphenyl(e.g.PhH=benzene,PhOH=phenol)苯基(PhH=苯,PhOH=苯酚)

TsOMemethylp-toluenesulfonate对甲苯磺酸比照1下polympolymeric集开的甲酯

DMAN,N-dimethylacetamideN,N’-两甲基乙酰胺

triglymetriethyleneglycoldimethyl ether3苦醇两甲醚

NBSN-bromo-succinimieeN-溴丁两酰亚胺

az distazeotropic distilation共沸粗馏

DMAPO4-dimethylaminopyridineoxide4⑶乙基硅烷两甲氨基吡啶氧化物

DHQdihydroquinine两氢奎宁

CTEABcetyltrimethylammoniumbuomide溴代106烷基3甲基铵

Dioxdioxane两恶烷/两氧6烷

DTEABdecyltriethylammoniumbromide溴代硼氢化钠开成癸基3乙基胺

TTFAthalium(3+)trifluoroacetate3氟乙酸铊(3+)

DMFN,N-dimethylformamideN-N-两甲基甲酰胺

TFSAtrifloromethanesulfonicacid3氟甲磺酸

n-BuOTSn-butyltosylate对甲苯磺酸正丁酯

DMSOdimethylsulfoxide两甲亚砜



乙酰乙酸乙酯酮式开成
念晓得乙酰氧基硼氢化钠
念晓得polympolymeric
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